Ink jet printhead with glass nozzle chambers

ABSTRACT

An ink jet printhead is provided. The printhead comprises: a silicon substrate; a CMOS layer comprising drive and control circuitry, the CMOS layer being formed on the silicon substrate; a passivation layer covering the CMOS layer; and a plurality of nozzles mounted on the passivation layer. Each nozzle comprises a chamber adapted to contain an ejectable liquid; and a droplet ejection actuator associated with each of the chambers respectively, the droplet ejection actuator being electrically connected to the drive circuitry and adapted to eject a droplet of the ejectable liquid from the nozzle. The chambers are comprised of a glass material.

CROSS REFERENCES TO RELATED APPLICATIONS

The present application is a divisional of U.S. application Ser. No. 10/407,212 filed Apr. 7, 2003, which is a continuation in part of U.S. application Ser. No. 09/113,122 filed on Jul. 10, 1998, now issued as U.S. Pat. No. 6,557,977, the entire contents of which are herein incorporated by reference

The following Australian provisional patent applications are hereby incorporated by reference. For the purposes of location and identification, US patents/patent applications identified by their US patent/patent application serial numbers are listed alongside the Australian applications from which the US patents/patent applications claim the right of priority.

US PATENT/PATENT CROSS-REFERENCED APPLICATION (CLAIMING AUSTRALIAN RIGHT OF PRIORITY FROM PROVISIONAL PATENT AUSTRALIAN PROVISIONAL DOCKET APPLICATION NO. APPLICATION) NO. PO7991 09/113,060 ART01 PO8505 6,476,863 ART02 PO7988 09/113,073 ART03 PO9395 6,322,181 ART04 PO8017 09/112,747 ART06 PO8014 6,227,648 ART07 PO8025 09/112,750 ART08 PO8032 09/112,746 ART09 PO7999 09/112,743 ART10 PO7998 09/112,742 ART11 PO8031 09/112,741 ART12 PO8030 6,196,541 ART13 PO7997 6,195,150 ART15 PO7979 6,362,868 ART16 PO8015 09/112,738 ART17 PO7978 09/113,067 ART18 PO7982 6,431,669 ART19 PO7989 6,362,869 ART20 PO8019 6,472,052 ART21 PO7980 6,356,715 ART22 PO8018 09/112,777 ART24 PO7938 09/113,224 ART25 PO8016 6,366,693 ART26 PO8024 6,329,990 ART27 PO7940 09/113,072 ART28 PO7939 6,459,495 ART29 PO8501 6,137,500 ART30 PO8500 09/112,796 ART31 PO7987 09/113,071 ART32 PO8022 6,398,328 ART33 PO8497 09/113,090 ART34 PO8020 6,431,704 ART38 PO8023 09/113,222 ART39 PO8504 09/112,786 ART42 PO8000 6,415,054 ART43 PO7977 09/112,782 ART44 PO7934 09/113,056 ART45 PO7990 09/113,059 ART46 PO8499 6,486,886 ART47 PO8502 6,381,361 ART48 PO7981 6,317,192 ART50 PO7986 09/113,057 ART51 PO7983 09/113,054 ART52 PO8026 09/112,752 ART53 PO8027 09/112,759 ART54 PO8028 09/112,757 ART56 PO9394 6,357,135 ART57 PO9396 09/113,107 ART58 PO9397 6,271,931 ART59 PO9398 6,353,772 ART60 PO9399 6,106,147 ART61 PO9400 09/112,790 ART62 PO9401 6,304,291 ART63 PO9402 09/112,788 ART64 PO9403 6,305,770 ART65 PO9405 6,289,262 ART66 PP0959 6,315,200 ART68 PP1397 6,217,165 ART69 PP2370 09/112,781 DOT01 PP2371 09/113,052 DOT02 PO8003 6,350,023 Fluid01 PO8005 6,318,849 Fluid02 PO9404 09/113,101 Fluid03 PO8066 6,227,652 IJ01 PO8072 6,213,588 IJ02 PO8040 6,213,589 IJ03 PO8071 6,231,163 IJ04 PO8047 6,247,795 IJ05 PO8035 6,394,581 IJ06 PO8044 6,244,691 IJ07 PO8063 6,257,704 IJ08 PO8057 6,416,168 IJ09 PO8056 6,220,694 IJ10 PO8069 6,257,705 IJ11 PO8049 6,247,794 IJ12 PO8036 6,234,610 IJ13 PO8048 6,247,793 IJ14 PO8070 6,264,306 IJ15 PO8067 6,241,342 IJ16 PO8001 6,247,792 IJ17 PO8038 6,264,307 IJ18 PO8033 6,254,220 IJ19 PO8002 6,234,611 IJ20 PO8068 6,302,528 IJ21 PO8062 6,283,582 IJ22 PO8034 6,239,821 IJ23 PO8039 6,338,547 IJ24 PO8041 6,247,796 IJ25 PO8004 09/113,122 IJ26 PO8037 6,390,603 IJ27 PO8043 6,362,843 IJ28 PO8042 6,293,653 IJ29 PO8064 6,312,107 IJ30 PO9389 6,227,653 IJ31 PO9391 6,234,609 IJ32 PP0888 6,238,040 IJ33 PP0891 6,188,415 IJ34 PP0890 6,227,654 IJ35 PP0873 6,209,989 IJ36 PP0993 6,247,791 IJ37 PP0890 6,336,710 IJ38 PP1398 6,217,153 IJ39 PP2592 6,416,167 IJ40 PP2593 6,243,113 IJ41 PP3991 6,283,581 IJ42 PP3987 6,247,790 IJ43 PP3985 6,260,953 IJ44 PP3983 6,267,469 IJ45 PO7935 6,224,780 IJM01 PO7936 6,235,212 IJM02 PO7937 6,280,643 IJM03 PO8061 6,284,147 IJM04 PO8054 6,214,244 IJM05 PO8065 6,071,750 IJM06 PO8055 6,267,905 IJM07 PO8053 6,251,298 IJM08 PO8078 6,258,285 IJM09 PO7933 6,225,138 IJM10 PO7950 6,241,904 IJM11 PO7949 6,299,786 IJM12 PO8060 09/113,124 IJM13 PO8059 6,231,773 IJM14 PO8073 6,190,931 IJM15 PO8076 6,248,249 IJM16 PO8075 09/113,120 IJM17 PO8079 6,241,906 IJM18 PO8050 09/113,116 IJM19 PO8052 6,241,905 IJM20 PO7948 09/113,117 IJM21 PO7951 6,231,772 IJM22 PO8074 6,274,056 IJM23 PO7941 6,290,861 IJM24 PO8077 6,248,248 IJM25 PO8058 6,306,671 IJM26 PO8051 6,331,258 IJM27 PO8045 6,110,754 IJM28 PO7952 6,294,101 IJM29 PO8046 6,416,679 IJM30 PO9390 6,264,849 IJM31 PO9392 6,254,793 IJM32 PP0889 6,235,211 IJM35 PP0887 6,491,833 IJM36 PP0882 6,264,850 IJM37 PP0874 6,258,284 IJM38 PP1396 6,312,615 IJM39 PP3989 6,228,668 IJM40 PP2591 6,180,427 IJM41 PP3990 6,171,875 IJM42 PP3986 6,267,904 IJM43 PP3984 6,245,247 IJM44 PP3982 6,315,914 IJM45 PP0895 6,231,148 IR01 PP0870 09/113,106 IR02 PP0869 6,293,658 IR04 PP0887 09/113,104 IR05 PP0885 6,238,033 IR06 PP0884 6,312,070 IR10 PP0886 6,238,111 IR12 PP0871 09/113,086 IR13 PP0876 09/113,094 IR14 PP0877 6,378,970 IR16 PP0878 6,196,739 IR17 PP0879 09/112,774 IR18 PP0883 6,270,182 IR19 PP0880 6,152,619 IR20 PP0881 09/113,092 IR21 PO8006 6,087,638 MEMS02 PO8007 6,340,222 MEMS03 PO8008 09/113,062 MEMS04 PO8010 6,041,600 MEMS05 PO8011 6,299,300 MEMS06 PO7947 6,067,797 MEMS07 PO7944 6,286,935 MEMS09 PO7946 6,044,646 MEMS10 PO9393 09/113,065 MEMS11 PP0875 09/113,078 MEMS12 PP0894 6,382,769 MEMS13

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

Not applicable.

FIELD OF THE INVENTION

The present invention relates to an ink jet printer device.

BACKGROUND OF THE INVENTION

Many different types of printing have been invented, a large number of which are presently in use. The known forms of print have a variety of methods for marking the print media with a relevant marking media. Commonly used forms of printing include offset printing, laser printing and copying devices, dot matrix type impact printers, thermal paper printers, film recorders, thermal wax printers, dye sublimation printers and ink jet printers both of the drop on demand and continuous flow type. Each type of printer has its own advantages and problems when considering cast, speed, quality, reliability, simplicity of construction and operation etc.

In recent years, the field of ink jet printing, wherein each individual pixel of ink is derived from one or more ink nozzles has become increasingly popular primarily due to its inexpensive and versatile nature.

Many different techniques of ink jet printing have been invented. For a survey of the field, reference is made to an article by J Moore, “Non-Impact Printing: Introduction and Historical Perspective”, Output Hand Copy Device, Editors R Dubeck and S Sherr, pages 207-220 (1988).

Ink Jet printers themselves come in many different forms. The utilization of a continuous stream of ink in ink jet printing appears to date back to at least 1929 wherein U.S. Pat. No. 1,941,001 by Hansell discloses a simple form of continuous stream electrostatic ink jet printing.

U.S. Pat. No. 3,596,275 by Sweet also discloses a process of continuous ink jet printing including a step wherein the ink jet stream is modulated by a high frequency electro-static field so as to cause drop separation. This technique is still utilized by several manufacturers including Elmjet and Scitex (see also U.S. Pat. No. 3,373,437 by Sweet et al).

Piezoelectric ink jet printers are also one form of commonly utilized ink jet printing device. Piezoelectric systems are disclosed by Kyser et. al. in U.S. Pat. No. 3,946,398 (1970) which utilizes a diaphragm mode of operation, by Zolten in U.S. Pat. No. 3,683,212 (1970) which discloses a squeeze mode of operation of a piezoelectric crystal, Stemme in U.S. Pat. No. 3,747,120 (1972) discloses a bend mode of piezoelectric operation, Howkins in U.S. Pat. No. 4,459,601 discloses a piezoelectric push mode actuation of the ink jet stream and Fischbeck in U.S. Pat. No. 4,584,590 which discloses a shear mode type of piezoelectric transducer element.

Recently, thermal ink jet printing has become an extremely popular form of ink jet printing. The ink jet printing techniques include those disclosed by Endo et al in GB 2007162 (1979) and Vaught et al in U.S. Pat. No. 4,490,728. Both the aforementioned references disclose ink jet printing techniques which rely upon the activation of an electrothermal actuator which results in the creation of a bubble in a constricted space, such as a nozzle, which thereby causes the ejection of ink from an aperture connected to the confined space onto a relevant print media. Printing devices utilizing the electro-thermal actuator are manufactured by manufacturers such as Canon and Hewlett Packard.

As can be seen from the foregoing, many different types of printing technologies are available. Ideally, a printing technology should have a number of desirable attributes. These include inexpensive construction and operation, high speed operation, safe and continuous long term operation etc. Each technology may have its oven advantages and disadvantages in the area is of cost, speed, quality, reliability, power usage, simplicity of construction operation, durability and consumables.

It would be desirable to create a more compact and efficient inkjet printer having an efficient and effective operation in addition to being as compact as possible.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective cross-sectional view of a single ink jet nozzle constructed in accordance with a preferred embodiment;

FIG. 2 is a close-up perspective cross-sectional view (portion A of FIG. 1), of a single ink jet nozzle constructed in accordance with a preferred embodiment;

FIG. 3 is an exploded perspective view illustrating the construction of a single ink jet nozzle in accordance with a preferred embodiment;

FIG. 4 provides a legend of the materials indicated in FIGS. 1 to 15; and

FIGS. 5 to 15 illustrate sectional views of the manufacturing steps in one form of construction of an ink jet printhead nozzle.

DESCRIPTION OF PREFERRED AND OTHER EMBODIMENTS

The ink jet designs shown here are suitable for a wide range of digital printing systems, from battery powered one-time use digital cameras, through to desktop and network printers, and through to commercial printing systems

For ease of manufacture using standard process equipment, the print head is designed to be a monolithic CMOS chip with MEMS post processing. For a general introduction to micro-electric mechanical systems (MEMS) reference is made to standard proceedings in this field including the proceedings of the SPIE (International Society for Optical Engineering), volumes 2642 and 2882 which contain the proceedings for recent advances and conferences in this field.

For color photographic applications, the print head is 100 mm long, with a width which depends upon the ink jet type.

IJ02

In a preferred embodiment, an ink jet print head is made up of a plurality of nozzle chambers each having an ink ejection port. Ink is ejected from the ink ejection port through the utilization of attraction between two parallel plates.

Turning initially to FIG. 1, there is illustrated a cross-sectional view of a single nozzle arrangement 210 as constructed in accordance with a preferred embodiment. The nozzle arrangement 210 includes a nozzle chamber 211 in which is stored ink to be ejected out of an ink ejection port 212. The nozzle arrangement 210 can be constructed on the top of a silicon wafer utilizing micro electromechanical systems construction techniques as will become more apparent hereinafter. The top of the nozzle plate also includes a series of regular spaced etchant holes, e.g. 213 which are provided for efficient sacrificial etching of lower layers of the nozzle arrangement 210 during construction. The size of the etchant holes 213 is signal enough that surface tension characteristics inhibit ejection from the holes 213 during operation.

Ink is supplied to the nozzle chamber 211 via an ink supply channel, e.g. 215.

Turning now to FIG. 2, there is illustrated a cross-sectional view of one side of the nozzle arrangement 210. A nozzle arrangement 210 is constructed on a silicon wafer base 217 on top of which is first constructed a standard CMOS two level metal layer 218 which includes the required drive and control circuitry for each nozzle arrangement. The layer 218, which includes two levels of aluminum, includes one level of aluminum 219 being utilized as a bottom electrode plate. Other portions 220 of this layer can comprise nitride passivation. On top of the layer 219 there is provided a thin polytetrafluoroethylene (PTFE) layer 221.

Next, an air gap 227 is provided between the top and bottom layers. This is followed by a further PTFE layer 228 which forms part of the lop plate 222. The two PTFE layers 221, 228 are provided so as to reduce possible stiction effects between the upper and lower plates. Next, a top aluminum electrode layer 230 is provided followed by a nitride layer (not shown) which provides structural integrity to the top electro plate. The layers 228-230 are fabricated so as to include a corrugated portion 223 which concertinas upon movement of the top plate 222.

By placing a potential difference across the two aluminum layers 219 and 230, the top plate 222 is attracted to bottom aluminum layer 219 thereby resulting in a movement of the top plate 222 towards the bottom plate 219. This results in energy being stored in the concertinaed spring arrangement 223 in addition to air passing out of the side air holes, e.g. 233 and the ink, being sucked into the nozzle chamber as a result of the distortion of the meniscus over the ink ejection port 212 (FIG. 1). Subsequently, the potential across the plates is eliminated thereby causing the concertinaed spring portion 223 to rapidly return the plate 222 to its rest position. The rapid movement of the plate 222 causes the consequential ejection of ink from the nozzle chamber via the ink ejection port 212 (FIG. 1). Additionally, air flows in via air gap 233 underneath the plate 222.

The ink jet nozzles of a preferred embodiment can be formed from utilization of semi-conductor fabrication and MEMS techniques. Turning to FIG. 3, there is illustrated an exploded perspective view of the various layers in the final construction of a nozzle arrangement 210. At the lowest layer is the silicon wafer 217 upon which all other processing steps take place. On top of the silicon layer 217 is the CMOS circuitry layer 218 which primarily comprises glass. On top of this layer is a nitride passivation layer 220 which is primarily utilized to passivate and protect the lower glass layer from any sacrificial process that may be utilized in the building up of subsequent layers. Next there is provided the aluminum layer 219 which, in the alternative, can form part of the lower CMOS glass layer 218. This layer 219 forms the bottom plate. Next, two PTFE layers 226, 228 are provided between which is laid down a sacrificial layer, such as glass, which is subsequently etched away so as to release the plate 222 (FIG. 2). On top of the PTFE layer 228 is laid down the aluminum layer 230 and a subsequent thicker nitride layer (not shown) which provides structural support to the top electrode stopping it from sagging or deforming. After this comes the top nitride nozzle chamber layer 235 which forms the rest of the nozzle chamber and ink supply channel. The layer 235 can be formed from the depositing and etching of a sacrificial layer and then depositing the nitride layer, etching the nozzle and etchant holes utilizing an appropriate mask before etching away the sacrificial material.

Obviously, print heads can be formed from large arrays of nozzle arrangements 210 on a single wafer which is subsequently diced into separate print heads. Ink supply can be either from the side of the wafer or through the wafer utilizing deep anisotropic etching systems such as high density low pressure plasma etching systems available from surface technology systems. Further, the corrugated portion 223 can be formed through the utilisation of a half tone mask process.

One form of detailed manufacturing process which can be used to fabricate monolithic ink jet print heads operating in accordance with the principles taught by the present embodiment can proceed utilizing the following steps:

1. Using a double sided polished wafer 240, complete a 0.5 micron, one poly, 2 metal CMOS process 242. This step is shown in FIG. 5. For clarity, these diagrams may not be to scale, and may not represent a cross section though any single plane of the nozzle. FIG. 4 is a key to representations of various materials in these manufacturing diagrams, and those of other cross referenced ink jet configurations.

2. Etch the passivation layers 246 to expose the bottom electrode 244, formed of second level metal. This etch is performed using Mask 1. This step is shown in FIG. 6.

3. Deposit 50 nm of PTFE or other highly hydrophobic material.

4. Deposit 0.5 microns of sacrificial material, e.g. polyimide 248.

5. Deposit 0.5 microns of (sacrificial) photosensitive polyimide.

6. Expose and develop the photosensitive polyimide using Mask 2. This mask is a gray-scale mask which defines the concertina edge 250 of the upper electrode. The result of the etch is a series of triangular ridges at the circumference of the electrode. This concertina edge is used to convert tensile stress into bend strain, and thereby allow the upper electrode to move when a voltage is applied across the electrodes. This step is shown in FIG. 7.

7. Etch the polyimide and passivation layers using Mask 3, which exposes the contacts for the upper electrode which are formed in second level metal.

8. Deposit 0.1 microns of tantalum 252, forming the upper electrode.

9. Deposit 0.5 microns of silicon nitride (Si₃N₄), which forms the movable membrane of the upper electrode.

10. Etch the nitride and tantalum using Mask 4. This mask defines the upper electrode, as well as the contacts to the upper electrode. This step is shown in FIG. 8.

11. Deposit 12 microns of (sacrificial) photosensitive polyimide 254.

12. Expose and develop the photosensitive polyimide using Mask 5. A proximity aligner can be used to obtain a large depth of focus, as the line-width for this step is greater than 2 microns, and can be 5 microns or more. This mask defines the nozzle chamber walls. This step is shown in FIG. 9.

13. Deposit 3 microns of PECVD glass 256. This step is shown in FIG. 10.

14. Etch to a depth of 1 micron using Mask 6. This mask defines the nozzle rim 258. This step is shown in FIG. 11.

15. Etch down to the sacrificial layer 254 using Mask 7. This mask defines the roof of the nozzle chamber, and the nozzle 260 itself. This step is shown in FIG. 12.

16. Back-etch completely through die silicon wafer 246 (with, for example, an ASE Advanced Silicon Etcher from Surface Technology Systems) using Mask 8. This mask defines the ink inlets 262 which are etched through the wafer 240. The wafer 240 is also diced by this etch.

17. Back-etch through the CMOS oxide layer through the holes in the wafer 240. This step is shown in FIG. 13.

18. Etch the sacrificial polyimide 254. The nozzle chambers 264 are cleared, a gap is formed between the electrodes and the chips are separated by this etch. To avoid stiction, a final rinse using supercooled carbon dioxide can be used. This step is shown in FIG. 14.

19. Mount the print heads in their packaging, which may be a molded plastic former incorporating ink channels which supply the appropriate color ink to the ink inlets at the back of the wafer.

20. Connect the print heads to their interconnect systems. For a low profile connection with minimum disruption of airflow, TAB may be used. Wire bonding may also be used if the printer is to be operated with sufficient clearance to the paper.

21. Hydrophobize the front surface of the print heads.

22. Fill the completed print heads with ink 266 and test them. A filled nozzle is shown in FIG. 15.

The presently disclosed ink jet printing technology is potentially suited to a wide range of printing system including: color and monochrome office printers, short run digital printers, high speed digital printers, offset press supplemental printers, low cost scanning printers high speed pagewidth printers, notebook computers with inbuilt pagewidth printers, portable color and monochrome printers, color and monochrome copiers, color and monochrome facsimile machines, combined printer, facsimile and copying machines, label printers, large format plotters, photograph copiers, printers for digital photographic “minilabs”, video printers, PHOTO CD (PHOTO CD is a registered trademark of the Eastman Kodak Company) printers, portable printers for PDAs, wallpaper printers, indoor sign printers, billboard printers, fabric printers, camera printers and fault tolerant commercial printer arrays.

It would be appreciated by a person skilled in the art that numerous variations and/or modifications may be made to the present invention as shown in the specific embodiments without departing from the spirit or scope of the invention as broadly described. The present embodiments are, therefore, to be considered in all respects to be illustrative and not restrictive. 

1. An ink jet printhead comprising: a silicon substrate; a CMOS layer comprising drive and control circuitry, said CMOS layer being formed on said silicon substrate; a passivation layer covering said CMOS layer, and a plurality of nozzles mounted on said passivation layer, each nozzle comprising: a chamber adapted to contain an ejectable liquid; and, at least one droplet ejection actuator associated with each of the chambers respectively, the droplet ejection actuator being electrically connected to the drive circuitry and adapted to eject a droplet of the ejectable liquid from the nozzle, wherein the chambers are comprised of a glass material.
 2. An ink jet printhead according to claim 1, wherein the glass material is silicon nitride.
 3. An ink jet printhead according to claim 1 wherein the printhead is a pagewidth printhead.
 4. An ink jet printhead according to claim 1, wherein the glass material is deposited by plasma enhanced chemical vapour deposition (PECVD).
 5. A method of ejecting drops of an ejectable liquid from an inkjet printhead, the printhead comprising: a silicon substrate; a CMOS layer comprising drive and control circuitry, said CMOS layer being formed on said silicon substrate; a passivation layer covering said CMOS layer, and a plurality of nozzles mounted on said passivation layer, each nozzle comprising: a chamber adapted to contain an ejectable liquid; and, at least one droplet ejection actuator associated with each of the chambers respectively, the droplet ejection actuator being electrically connected to the drive circuitry, wherein the are comprised of a glass material; the method comprising the steps of: placing the ejectable liquid into contact with the drop ejection actuator; and actuating the droplet ejection actuator using said drive circuitry such that a droplet of an ejectable liquid is ejected from the corresponding nozzle.
 6. A method according to claim 5, wherein the glass material is silicon nitride.
 7. A method according to claim 5, wherein the printhead is a pagewidth printhead. 